I prime with automotive spray primer in white. As I am painting metal models the priming is a useful starter. I like the sort of highlighting that a white undercoat provides, and at my scale (6mm) the generally lightening effect is also helpful.
I usually base coat on top of the primer with Testors Model Master sprays. I then weather and detail with Acrylics.
The best tips for preventing glopping from the sprays are:
1) Shake a lot, quite vigorously, before and periodically through the time you are spraying.
2) Spray with broad sweeping motions with at least 12 inches (300mm) and better 16-18 inches (400-450mm) from nozzle to model. I usually paint 10 or 15 models at once, so that I can use very broad sweeping motions effectively. At larger scales that may not be practical.
3) Only spray when the temperature and humidity levels are right! If the air is too cold or the humidity is too high you may get concentrations, globs and runs in the paint job. If it is too hot or the humidity too low the paint will dry too fast, sometimes drying into micro-drops while in the air, leading to a sand-paper like finish.
Sometimes I do the base coat with Acrylics using a brush, just due to the selection of the color or the small size of the lot I'm painting. But even then, the priming is done with a spray white automotive primer.
White automotive spray primer. Testor Model Master (Dessert Sand above, Olive green below) spray base coat. Detailing and weathering with Acrylics. That's my most common approach.
As to buying, I have never bought paints through online or mail order. Always in shops. But then I'm in a big urban area in California, so even if I did buy through the post it would not be particularly relevant …
-Mark
(aka: Mk 1)